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Benzidine (CAS#92-87-5)

Ngwongwo kemịkalụ:

Usoro ihe omimi C12H12N2
Molar Mass 184.24
Njupụta 1.25
Ebe Na-agbaze 127-128 Celsius C
Ebe Boling 402°C
Ebe mgbari 11°C
Mmiri Solubility Na-edozi obere. <0.1 g/100 ml na 22ºC
Solubility Soluble na ethanol (US EPA, 1985) na ether (1 g/50 ml) (Windholz et al., 1983)
Uzuoku nrịbama Dabere na uru njupụta uzuoku akọwapụtara nke 6.36 (Sims et al., 1988), a na-agbakọ nrụgide vepo ka ọ bụrụ 0.83 na 20 Celsius.
Ọdịdị dị ọcha
Agba Grayish-edo edo, crystalline ntụ ntụ; kristal na-acha ọcha ma ọ bụ sltlyreddish, ntụ ntụ
Oke ngosi N'ihi na ọ bụ ọrịa carcinogen ma na-amịnye ya ngwa ngwa site na akpụkpọ ahụ, ọ nweghị TLV ekenyela ya. Ngosipụta kwesịrị ịdị na nke zuru oke. Achọpụtara Carcinogen mmadụ (ACGIH); Carcinogen mmadụ (MSHA); Carcinogen (O
Merck 13,1077
BRN 742770
pKa 4.66 (na 30 ℃)
Ọnọdụ Nchekwa 2-8 Celsius C
Nkwụsi ike Kwụsie ike. Na-agbanyụ ọkụ. Ekwekọrịtaghị na ndị ọrụ oxidizing siri ike.
Ntụgharị ntụgharị uche 1.6266 (atụmatụ)
Njirimara anụ ahụ na kemịkalụ ntụ ntụ crystalline ọcha ma ọ bụ ọbara ọbara. Ebe mgbaze 125 ℃, esi esi 400 ℃, (98.7kPa), ikwu njupụta 1.250 (20/4 ℃), soluble na esi ethanol, acetic acid na itughari hydrochloric acid, ubé soluble na ether, ubé soluble na esi mmiri, dị nnọọ ntakịrị soluble. soluble na mmiri oyi. Agba agba ọchịchịrị na ikuku na ìhè. Ihe nyocha nyocha na-abụkarị benzidine hydrochloride ma ọ bụ acetate nwere solubility dị elu, a na-ejikarị sulfate eme ihe na ụlọ ọrụ. Benzidine acetate bụ ọcha ma ọ bụ ihe fọrọ nke nta ka ọ bụrụ kristal ọcha, soluble na mmiri, acetic acid na hydrochloric acid, ma jiri ya mee ihe dị ka ihe ngosi [36341-27-2]. benzidine hydrochloride (531-85-1). Benzidine sulfate bụ kristal na-acha ọcha ntụ ntụ ma ọ bụ obere kristal dị ka kristal, soluble na ether, dị ntakịrị soluble na mmiri, itughari acid na mmanya [21136-70-9].

Nkọwa ngwaahịa

Mkpado ngwaahịa

Koodu ihe egwu R45 - nwere ike ibute ọrịa kansa
R22 - na-emerụ ma ọ bụrụ na iloro ya
R50/53 - Na-egbu egbu maka ihe ndị dị n'ime mmiri, nwere ike ịkpata mmetụta ọjọọ na-adịte aka na gburugburu mmiri.
R52/53 - Na-emerụ ihe ndị dị n'ime mmiri, nwere ike ịkpata mmetụta ọjọọ na-adịte aka na gburugburu mmiri.
R39/23/24/25 -
R23/24/25 - Na-egbu egbu site na iku ume, na kọntaktị na akpụkpọ ahụ ma ọ bụrụ na iloro ya.
R11 - Na-agba ọkụ nke ukwuu
R36 / 37/38 - na-akpasu iwe na anya, usoro iku ume na akpụkpọ ahụ.
R20/21/22 - na-emerụ ahụ site na iku ume, na kọntaktị na akpụkpọ ahụ ma ọ bụrụ na loro ya.
R51/53 - Ihe na-egbu egbu nye ihe ndị dị ndụ na mmiri, nwere ike ịkpata mmetụta ọjọọ na-adịte aka na gburugburu mmiri.
R67 - Vapors nwere ike ime ka iro ụra na dizziness
Nkọwapụta nchekwa S53 – Zere ikpughe – nweta ntuziaka pụrụ iche tupu ojiji.
S45 - Ọ bụrụ na ihe mberede ma ọ bụ ọ bụrụ na ahụ adịghị gị mma, chọọ ndụmọdụ ahụike ozugbo (gosi akara ahụ mgbe ọ bụla enwere ike.)
S60 - A ga-ekpochapụ ihe a na akpa ya dị ka ihe mkpofu dị ize ndụ.
S61 – Zere ntọhapụ na gburugburu ebe obibi. Rụtụ aka na ntuziaka pụrụ iche / mpempe data nchekwa.
S36/37 - Yiri uwe nchebe kwesịrị ekwesị na uwe aka.
S16 - Wepụ ya na isi mmalite nke mgbanye.
S7 - Debe akpa ahụ nke ọma.
S36 - Yiri uwe nchebe kwesịrị ekwesị.
S26 - N'ihe banyere kọntaktị na anya, kpochaa ozugbo na ọtụtụ mmiri ma chọọ ndụmọdụ ahụike.
NJ UN UN 1885 6.1/PG 2
WGK Germany 3
RTECS DC9625000
Koodu FLUKA BRAND F 8
Koodu HS 29215900
Klas Hazard 6.1 (a)
Otu nkwakọ ngwaahịa II
Nsi Nnukwu ọnụ ọnụ LD50 maka ụmụ oke 214 mg/kg, oke 309 mg/kg (kwuru, RTECS, 1985).

 

Okwu mmalite

Benzidine (nke a makwaara dị ka diphenylamine) bụ ngwakọta organic. Ihe na-esonụ bụ mmalite nke ọdịdị ya, ojiji ya, ụzọ mmepụta ya na ozi nchekwa:

 

Ogo:

- Ọdịdị: Benzidine bụ ọcha na-acha odo odo kristal siri ike.

- Solubility: ihe na-adịghị ike na mmiri, soluble na organic solvents dị ka alcohols, ethers, wdg.

- Akara: Ọ bụ electrophile nwere njirimara nke mmeghachi omume ngbanwe electrophilic.

 

Jiri:

- A na-eji Benzidine eme ihe n'ọtụtụ ebe n'ọhịa nke njikọ organic. Enwere ike iji ya dị ka ihe eji eme ihe na etiti sịntetik maka kemịkalụ dị ka ịjiji, pigmenti, plastik, wdg.

 

Usoro:

- A na-akwado Benzidine site na mbelata dinitrobiphenyl, mkpochapụ radieshon nke haloaniline, wdg.

- Ụzọ nkwadebe nke oge a gụnyere njikọ organic nke amines aromatic, dị ka mmeghachi omume nke mkpụrụ diphenyl ether na amino alkanes.

 

Ozi nchekwa:

- Benzidine na-egbu egbu ma nwee ike ịkpasu iwe na imebi ahụ mmadụ.

- Mgbe a na-eji benzidine eme ihe, ekwesịrị ịkpachara anya ka ọ ghara imetụ akpụkpọ ahụ na ikuku ume, na a ga-eyi ihe nchekwa dịka uwe aka, ugogbe anya nchebe na ihe mkpuchi ma ọ bụrụ na ọ dị mkpa.

- Mgbe benzidine batara na akpụkpọ ahụ ma ọ bụ anya, ekwesịrị iji mmiri buru ibu sachaa ya ozugbo.

- Mgbe ị na-echekwa ma na-eji benzidine, lezie anya ka ị zere kọntaktị na ihe ndị dị ndụ na oxidants iji gbochie ọkụ ma ọ bụ mgbawa.

 


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